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Methylacetic acid

CAS No.: 79-09-4

  • Molecular Formula: C₃H₆O₂
  • Molecular Weight: 74.08 g/mol

Chemical type

  • Short-chain carboxylic acid (C₃) from biomass pyrolysis bio-oil
[1]
  • Chemical preservative / Additive
[2]

Key properties

  • Abundant in lignocellulosic pyrolysis bio-oils (mainly C₁–C₃ acids)
  • Low carbon number, unsuitable for direct use as gasoline or aviation fuel
  • Undergoes ketonisation (C–C coupling) with deoxygenation (loss of CO₂ and H₂O)
[1]
  • Strong antimicrobial agent (effective against molds, yeasts, and undesirable bacteria like Clostridium and Enterobacter)
  • Antimitotic effect (inhibits microbial growth)
  • Can act as a fungicide and bactericide in forage preservation
[2]
  • Model compound for bio-oil upgrading studies
  • Starting material for self-ketonisation to 3-pentanone (biofuel precursor)
  • Tested in 50:50 mixtures with real pyrolysis bio-oil to simulate industrial upgrading
[1]
  • Treatment for bermudagrass silage (applied at 0.5% and 1.0% of forage fresh weight)
  • Improves silage preservation and aerobic stability
  • Suppresses proteolytic bacteria, leading to higher crude protein preservation
  • Reduces butyric acid and ammonia-N concentrations in silage
[2]

Classification by use

  • Biomass-derived feedstocks
  • Intermediates for sustainable aviation fuel (SAF) production
[1]
  • Chemicals used in agriculture (forage preservation)
  • Feed additives / Silage additives
[2]

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  1. [Cite:1] Dataset on the ketonisation of pure propionic acid and its mixture with pyrolysis bio-oil over metal oxide catalysts into 3-pentanone a biofuel precursor, Data in Brief, Volume 61, August 2025, 111898
  2. [Cite:2] Nutritive value and fermentation characteristics of bermudagrass silage treated with propionic acid and microbial inoculant, Applied Animal Science, Volume 42, Issue 1, February 2026, Pages 9-18