4,6-Bis(diphenylphosphino)-10H-phenoxazine

CAS: 261733-18-0

Category: Organic Intermediates

PurityTechnical Grade ≥97%; Research Grade ≥98%; Catalyst Grade ≥99%; Electronic Grade ≥99.5%
Molecular FormulaC36H27NOP2
Molecular Weight547.55
AppearanceWhite to pale yellow crystalline powder
Packaging1 g, 5 g, 10 g, 25 g, 100 g amber glass bottle or fluorinated HDPE bottle; vacuum-sealed aluminum foil bag under nitrogen for bulk packaging
Testing IndicatorsAppearance — Visual inspection; Identification — ¹H NMR, ¹³C NMR, ³¹P NMR, FTIR and HRMS; Purity — HPLC (UV) and/or GC where applicable; Assay — HPLC area normalization; Phosphine oxide impurity — ³¹P NMR or HPLC; Water content — Karl Fischer titration (GB/T 6283); Residual solvents — GC (USP <467>); Melting point — Capillary melting point determination; Elemental analysis — CHN elemental analyzer.
Storage NotesStore in a tightly sealed container under dry nitrogen or argon in a cool, dry, well-ventilated area. Protect from moisture, oxygen, direct sunlight, and heat. Long-term storage at 2–8°C under inert atmosphere is recommended. Minimize exposure to air during handling.
Lead Time10 days
A sterically demanding bidentate phosphine ligand widely used in transition-metal catalysis. Commonly employed in palladium-, nickel-, rhodium-, and iridium-catalyzed cross-coupling reactions including Buchwald-Hartwig amination, Suzuki-Miyaura coupling, Negishi coupling, Kumada coupling, and C-N/C-C bond formation. Also used in catalyst development, pharmaceutical intermediate synthesis, fine chemical production, and organometallic research.