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Glycol carbonate

CAS No.: 96-49-1

  • Molecular Formula: C₃Hβ‚„O₃
  • Molecular Weight: 88.06 g/mol

Chemical type

  • Cyclic carbonate
  • Organic solvent
[1]
  • Cyclic organic carbonate (high-boiling electrolyte solvent)
[2]

Key properties

  • High dielectric constant
  • Reduces at β‰ˆ3.1 V on anode surfaces
  • LUMO energy of -0.17 eV
  • Forms part of baseline electrolyte mixtures
  • Decomposition suppressed by additives like FEC and SD
[1]
  • High polarity and reactivity
  • Strong thermal stability at elevated temperatures
  • High boiling point (suitable for recovery via distillation)
  • Can be recovered with high purity (~96.9%)
[2]
  • Co-solvent (3:7 wt. with EMC) in LiPF₆-based electrolytes
  • Supports SEI formation in LIBs
  • Avoided in EC-free formulations for improved stability
[1]
  • Raw material for biodegradable polyester synthesis (PES, PESG)
  • Electrolyte solvent in lithium-ion batteries
  • Intermediate for polymer production
[2]

Classification by use

  • Battery electrolyte solvents
  • Components for high-permittivity mixtures

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  1. [Cite:1] Sulfonyl diimidazole to stabilize fluoroethylene carbonate-based SEI in high-voltage Li ion cells with a SiOx containing negative electrode, Energy Storage Materials, Volume 72, September 2024, 103735
  2. [Cite:2] Valorization of ethylene carbonate recovered from spent lithium-ion battery electrolytes: synthesis and properties of biodegradable poly ethylene succinate-co-ethylene glycol (PESG) copolyesters; RSC Advances, Volume 16, Issue 7, 3 February 2026, Pages 5785-5794